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Water Quality and Succulents

Can any of you tell me if the ph and/or hardness of water can affect the plants? Does tap water with a high mineral content and very alkaline seem to have negative affects? Such as dark spots on leaves? Our tap water is what we call "liquid rock". I am thinking of using rainwater to water all my plants, which are indoors in a sunroom with lots of fresh air in good weather. Any opinions? I use only bottled water for all my African violets.

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