If possible, I would stain the trim around the door to match the door in so that it just blends in.

And just leave the window trim right next to the door similar to the rest of the house?

^^^ yes

Trying to get a better grasp of what's going on here...

Is this a new build?

A remodel?

Is the trim already "finished", as in has it been stained or sealed?

Is the trim throughout the rest of the home the same?

The jamb extensions on the window appear to be painted, what's the plan there?

Having a different color door than the trim surrounding it is not entirely uncommon, although you have a lot going on there with that combined with the windows/jambs that appear to be white or beige. If the window is to remain as is, and this "scheme" matches the rest of the house, you could consider painting the interior side of the door to match that. I'll defer to those that specialize in design here, however that would look better to my eye and create some consistency.

If the window is to remain as is, and this "scheme" matches the rest of the house, you could consider painting the interior side of the door to match that.