I would center the dresser on the wall, not on the bed. It will look fine!

Thank you! I think so too!

How is it going to look when the door is closed? Do you have room for a small chair or a tall plant in the corner?

Can you please show photos of all 4 walls of the room? Would it be possible to place the dresser under the window?

I would center it between the edge of the open door and the wall. If it looks 'off' when the door is closed, I'd hang a full length mirror on the wall behind the door (when it's open) that will only show when the door is closed. It will provide some balance (and be useful). Your room is very pretty!

The dresser is small and looks like the size of a nightstand. Consider putting it on the side of the bed and putting a larger dresser on that wall.