In such a small space, I think it'd look too busy to bring in another bright color like the orange red you mention.

I would choose a pale blue/green that is in the background of the canvas over the bed. That would tie together the art, the darker blue/green bedpillows, and the bench and nightstand.

My second choice would be plain white to match the white bedframe, blanket, and blinds.

You've done a GREAT job with this room so far. It looks so cute! I'd think about a pale blue for the bench. You already have the cute orangey accent colors in the blanket and the clock......

But whatever you choose, kudos to the cute and comfy charming room. And it has a lot of personality too!

I am not a pro, not a pro, not a pro. But, I like the bench, and think it's functional for exactly the reason you stated first--you need a place to set stuff. I like your chippy paint ideas. try it! If it's not your favorite, you can paint over it. I like the idea of hooks above the bench, as well. But I'd put them in the far corner, so no one hits their head on them while they're making the bed.

I like your blue/red paint idea, too! And if it doesn't come out looking how you hope, you could go for a distressed blue & white, or just blue.

Can you walk around the bench? It is cute, but how do you get in and out of bed on the side next to the wall?

I like your idea of the aqua with a bit of red peeking through from underneath. I would do a simple white for the side table. Instead of hooks, you can add something like this to the wall. It opens up to hang clothes then folds down so they're not in the way.