If the sink drain is in the correct location, center the faucet on the window. That will help disguise the asymmetric placement of the sink.

Thanks! We are installing new plumbing since we are relocating the kitchen.

Sorry I meant the drain hole in the sink; it's better if the faucet is located to flow directly above the hole, to decrease splashing. But--I don't know if that is a must. You could double check that info on the plumbing forum.

Have you unpacked and dry fit the cabinets? I'd do that before anything, but centering the faucet and sink under the window would be #1 for me. Maybe you'll have to order a wider base cabinet for the left of the sink (27" instead of 24") to avoid 4" of fillers.

Symmetry is overrated.

Don’t move the sink to the left. That would decrease the function of your counter space. I would personally be more bothered by having the faucet off-center from the sink for seemingly no reason than I would be bothered by the faucet being off-center from the window(s). As per the above poster, know thyself—which do you prefer?

Why can’t the faucet go where ever you want it?

If the faucet is centered on the windows then when you look straight ahead you'll be look directly at the space/trim between the windows. That would drive me crazy. I'd probably center the sink on the opening and replace the window to a configuration (e.g., a large single window) that didn't block the view.

For crying out loud its a faucet ad so what if it is in front of the center where the wood is on the window , It might actually highlight the faucet.