Yes, you can. And as with other things, mixing straight lines and curves can be a good thing. If you can get fuller pictures of these or similar, make a mood board arrangement of pieces to see what you think.

Yes, they are complementary and not matchey matchey (not necessarily a bad thing). Are you gong to have two of these chairs with the sofa? Or a second different chair?

thank you I have 2 chairs… what is a mood arrangement ?

To help things along - I would add pillows to the couch that have some caramel tones and then add some textured cream & white pillows to the chairs - other colors can be added in too, i woukld just make sure the caramel and white are represented

It would be good to bring the color of the chair into the room with additional items like art, pillows, throw etc.

They look nice together.