What are the windows made of?

If you want, you can always put some painters tape on the trim, paint it black, and remove it.

Here is wood trim painted black around white windows.

It depends on what you are doing in the rest of the room, but it would not be my choice.

@windows on Washington…My windows are made out of Vinyl.

@BeverlyFLADeziner: I have an open concept floor plan. The kitchen is open to a combination living room and dining room. My color theme is black, white, and gold. All of my walls and mouldings are white, the kitchen cabinets and island is white, and the countertops are white with grey veining. Im going to paint my kitchen island black. I also plan on painting my doors black.